2 00:00:10,909 --> 00:00:15,043 Fossil fuel combustion is basically taking 3 00:00:15,043 --> 00:00:19,100 a jolt from that battery of the biosphere. 4 00:00:19,100 --> 00:00:21,680 We're digging up some buried organic carbon, and 5 00:00:21,680 --> 00:00:25,490 reacting with oxygen to get the energy back. 6 00:00:25,490 --> 00:00:28,200 One thing that may occur to you is, Does that 7 00:00:28,200 --> 00:00:31,420 mean we're going to use up the oxygen in the atmosphere? 8 00:00:31,420 --> 00:00:35,640 That would be like draining the battery of a biosphere all the way dead. 9 00:00:35,640 --> 00:00:40,730 Fortunately, for us, most of the buried organic carbon in the earth is in an 10 00:00:40,730 --> 00:00:47,120 inconvenient form to use as a fuel. limestone rock is a big white thing. 11 00:00:47,120 --> 00:00:52,790 But it has maybe a few tenths of a percent of organic carbon, 12 00:00:52,790 --> 00:00:57,570 mixed in with it, in a form that we could never extract, and put into a gas tank. 13 00:00:57,570 --> 00:01:00,690 Most of the buried organic carbon is 14 00:01:00,690 --> 00:01:03,700 not suitable as a fossil fuel. 15 00:01:03,700 --> 00:01:07,950 There are three basic types of fossil fuels. 16 00:01:07,950 --> 00:01:12,320 And the most abundant of them, and therefore the most important one for the 17 00:01:12,320 --> 00:01:19,120 future of Earth's climate, is coal. Coal is fossil 18 00:01:19,120 --> 00:01:26,000 plant material that was protected from being respired by, being deposited 19 00:01:26,000 --> 00:01:30,580 in a swamp. If you have a soil that has lots of 20 00:01:30,580 --> 00:01:35,380 water, it's very waterlogged, it's hard for oxygen from the air to get down in 21 00:01:35,380 --> 00:01:40,940 there, so plant material, leaves, roots, 22 00:01:40,940 --> 00:01:46,120 or mosses, can accumulate as thick deposits of 23 00:01:46,120 --> 00:01:51,360 very pure organic carbon known as peat. And then when that peat 24 00:01:51,360 --> 00:01:57,350 is cooked, it it matures into what we call coal. 25 00:01:57,350 --> 00:02:00,090 There are two different types of coal. 26 00:02:01,430 --> 00:02:06,530 Coal that is formed in salt-water conditions 27 00:02:06,530 --> 00:02:09,620 tends to have more sulfur in it, 28 00:02:09,620 --> 00:02:13,370 because sea water has sulfur in the form of sulfate. 29 00:02:13,370 --> 00:02:16,420 Whereas, coal that's formed in fresh water conditions tends to have 30 00:02:16,420 --> 00:02:18,980 less sulfur in it. 31 00:02:18,980 --> 00:02:21,840 You already know about the sulfate aerosols. 32 00:02:21,840 --> 00:02:23,810 This is where they come from. 33 00:02:23,810 --> 00:02:26,770 When there is sulfur in the coal that's released to the atmosphere, 34 00:02:26,770 --> 00:02:30,570 it makes these little droplets, which scatter light, change 35 00:02:30,570 --> 00:02:33,865 the properties of clouds, the indirect effect, and all that. 37 00:02:34,760 --> 00:02:43,220 Coal is basically mostly elemental carbon. 38 00:02:43,220 --> 00:02:48,910 The oxidation state of carbon just by itself is zero. 39 00:02:48,910 --> 00:02:52,080 Coal is halfway between 40 00:02:52,080 --> 00:02:55,140 the most oxidized form and the most reduced form. 41 00:02:55,140 --> 00:02:59,760 It only has half as much energy per carbon as natural gas, which is the most 42 00:02:59,760 --> 00:03:06,020 reduced form of carbon. Coal is also not particularly convenient 43 00:03:06,020 --> 00:03:10,080 as a fossil fuel, compared to the other ones, because it's in a solid form. 44 00:03:10,080 --> 00:03:16,930 And so, mostly what coal is used for is to generate electricity 45 00:03:16,930 --> 00:03:22,280 by burning it and using the heat to boil water to make steam. 46 00:03:22,280 --> 00:03:25,490 And then using the steam to drive the turbine, 47 00:03:25,490 --> 00:03:27,680 as opposed to oil which is in a nice liquid 48 00:03:27,680 --> 00:03:29,670 form that you can put in a gas tank. 49 00:03:30,910 --> 00:03:34,300 Coal is the most abundant of the fossil fuels. 50 00:03:34,300 --> 00:03:38,620 Here are approximate inventories of different types of fossil fuels. 51 00:03:38,620 --> 00:03:45,220 Rhese are somewhat fuzzy numbers because how much coal we think can be 52 00:03:45,220 --> 00:03:50,550 extracted from the Earth depends on how far we're willing to go to 53 00:03:50,550 --> 00:03:51,000 get it. 54 00:03:51,000 --> 00:03:56,100 And on technological improvements in coal mining, things like that. 55 00:03:56,100 --> 00:03:59,844 But in general there's at least 10 times more coal 56 00:03:59,844 --> 00:04:04,069 or maybe 50 times more coal than the other fossil fuels. 57 00:04:04,069 --> 00:04:09,202 The question of what Earth's climate will look like in the year 58 00:04:09,202 --> 00:04:14,293 2100 and beyond depends largely on what happens to that coal.