2 00:00:10,434 --> 00:00:14,146 We're in the process of trying to figure out why the temperature 3 00:00:14,146 --> 00:00:18,890 up high in the atmosphere is different from the temperature at the ground. 4 00:00:18,890 --> 00:00:21,270 And the reason why we're doing that is because 5 00:00:21,270 --> 00:00:24,620 that temperature difference is what drives the green house effect, 6 00:00:24,620 --> 00:00:27,412 because we're absorbing the light from the warm ground 7 00:00:27,412 --> 00:00:30,778 and replacing it with light from the cold upper atmosphere. 8 00:00:30,778 --> 00:00:36,360 We started the class with a very simple model of 9 00:00:36,360 --> 00:00:41,130 the temperature in the atmosphere as a function of height with the layer model. 10 00:00:41,130 --> 00:00:45,630 Where we don't actually have a vertical coordinate exactly, 11 00:00:45,630 --> 00:00:48,600 we just have this pane of glass sitting there and 12 00:00:48,600 --> 00:00:51,640 it has a different temperature than the ground 13 00:00:51,640 --> 00:00:54,120 because of the way the light is carrying the energy around. 14 00:00:55,690 --> 00:01:02,010 so if you were to take the atmosphere and freeze it like some kind of 15 00:01:02,010 --> 00:01:05,810 aerogel that would be like air, but it couldn't move, and 16 00:01:05,810 --> 00:01:09,210 the only thing that was carrying heat around was light, you would 17 00:01:09,210 --> 00:01:14,040 have a temperature difference between the ground and high altitude that 18 00:01:14,040 --> 00:01:16,320 is actually much stronger than the 19 00:01:16,320 --> 00:01:18,780 temperature difference that you actually observe. 20 00:01:18,780 --> 00:01:22,680 It would get colder about 16 degrees for 21 00:01:22,680 --> 00:01:25,870 every kilometer that you go up in the atmosphere. 22 00:01:25,870 --> 00:01:27,500 It turnes out that 23 00:01:27,500 --> 00:01:32,330 that much of a temperature difference is unstable to convection, 24 00:01:32,330 --> 00:01:36,600 because you have buoyant air 25 00:01:36,600 --> 00:01:41,720 underneath dense air, and so it's unstable, it wants to turn over. 26 00:01:41,720 --> 00:01:47,620 Convection tends to mix things in a column of fluid. 27 00:01:47,620 --> 00:01:54,020 You heat it from below or you cool it from the top and it, and it stirs and mixes 29 00:01:54,020 --> 00:01:57,530 It's complicated in a gas because when 30 00:01:57,530 --> 00:02:02,190 the air rises it expands and therefore cools. 31 00:02:02,190 --> 00:02:05,690 And so, the product of convection doesn't make 32 00:02:05,690 --> 00:02:08,430 the temperature of the whole column the same 33 00:02:08,430 --> 00:02:10,760 the way it would in water, which doesn't expand and 34 00:02:10,760 --> 00:02:13,650 cool in the same way, because it's not compressible. 35 00:02:13,650 --> 00:02:18,300 But this is the temperature profile that you would get if you just had expansion 36 00:02:18,300 --> 00:02:20,450 of gas as we've talked about. 37 00:02:20,450 --> 00:02:24,210 And it would give you temperature difference as you go 38 00:02:24,210 --> 00:02:28,430 up in the atmosphere of about ten degrees C per kilometer. 39 00:02:28,430 --> 00:02:30,950 So that's better, that's in the right direction. 40 00:02:30,950 --> 00:02:33,950 But actually, the observed temperature gradient in the 41 00:02:33,950 --> 00:02:38,080 atmosphere is about six degrees C for kilometer. 42 00:02:38,080 --> 00:02:43,520 So added to this cooling aloft from expansion we 43 00:02:43,520 --> 00:02:46,990 have to add some heating, and the heating 44 00:02:46,990 --> 00:02:50,240 is coming from water vapor and latent heat. 45 00:02:55,090 --> 00:02:59,970 When you boil water you've got H2O in liquid and H2O 46 00:02:59,970 --> 00:03:04,060 in the gas, so it seems like a pretty boring chemical reaction. 47 00:03:04,060 --> 00:03:07,700 But you also have to add a significant amount of heat to the 48 00:03:07,700 --> 00:03:13,220 molecules to turn them into vapor from the liquid. This is called latent heat. 49 00:03:13,220 --> 00:03:17,150 So if you turn the burner on 50 00:03:17,150 --> 00:03:20,320 underneath a pan of water and boil some water, 51 00:03:20,320 --> 00:03:23,150 the temperature in the pan of water will rise 52 00:03:23,150 --> 00:03:26,420 until it reaches the boiling point, and then 53 00:03:26,420 --> 00:03:29,430 it stays at that boiling point and doesn't get any hotter 54 00:03:29,430 --> 00:03:32,200 because the water can't get hotter than that without boiling. 55 00:03:32,200 --> 00:03:35,330 So you're putting heat into this all the time, 56 00:03:35,330 --> 00:03:37,920 the flame is still burning, but the temperature doesn't go up. 57 00:03:37,920 --> 00:03:39,660 Where does that heat go? 58 00:03:39,660 --> 00:03:45,450 It goes into making the vapor. And then you've got steam coming off 59 00:03:45,450 --> 00:03:49,020 the top, like out of a teapot, you can see steam coming off. 60 00:03:49,020 --> 00:03:54,740 Actually, what you see there, is not the water vapor, water vapor itself, 61 00:03:54,740 --> 00:03:59,960 real legitimate gas H2O, is invisible, we can't see it. 62 00:03:59,960 --> 00:04:02,360 There's water vapor in between you and me right 63 00:04:02,360 --> 00:04:05,250 now and, and we can't see it because it's invisible. 64 00:04:05,250 --> 00:04:07,120 What you see coming out of the teapot 65 00:04:07,120 --> 00:04:10,810 is little droplets of water that that interact 66 00:04:10,810 --> 00:04:11,766 with the light. 67 00:04:11,766 --> 00:04:14,730 But, you must pay attention to those droplets 68 00:04:14,730 --> 00:04:16,970 of water, because if you stick your hand in there 69 00:04:16,970 --> 00:04:19,830 when steam comes out you will burn yourself severely, 70 00:04:19,830 --> 00:04:24,460 and it's not because the steam is all that hot. 71 00:04:24,460 --> 00:04:27,000 212 degrees Fahrenheit (100 deg C) would be 72 00:04:27,000 --> 00:04:29,150 like a bread warming oven, you could stick your hand 73 00:04:29,150 --> 00:04:34,340 into a, a 200 degree oven (~95C), and the air would not burn you. 74 00:04:34,340 --> 00:04:36,310 But the steam would condense on your skin 75 00:04:37,490 --> 00:04:42,340 and release all of its heat, 76 00:04:42,340 --> 00:04:47,420 you get a very strong burn from that, because of this latent heat. 77 00:04:52,600 --> 00:04:57,550 The way that water vapor works in the air is, 78 00:04:57,550 --> 00:05:02,820 the amount of water vapor that you want to have, the pressure of vapor, 79 00:05:02,820 --> 00:05:08,530 of gas, of water gas, is a very strong function of the temperature. 80 00:05:08,530 --> 00:05:13,660 And it makes sense, because if you make it all warmer, the water 81 00:05:13,660 --> 00:05:18,150 molecules, they want to break free of the constraints of the liquid, and 82 00:05:18,150 --> 00:05:23,160 they want to go into the vapor phase. So as the temperature rises, the amount of 83 00:05:23,160 --> 00:05:28,710 water vapor that you find goes up very strongly. 84 00:05:28,710 --> 00:05:35,520 Now this curve, represents what's called the equilibrium amount of water vapor. 85 00:05:35,520 --> 00:05:39,270 In other words, that's the state at some temperature, 86 00:05:39,270 --> 00:05:43,240 if you have water available liquid, and you let it 87 00:05:43,240 --> 00:05:47,610 sit for a long time, it'll evaporate until it reaches that line. 88 00:05:47,610 --> 00:05:52,520 Or if you have too much, it'll tend to condense until it reaches that line. 89 00:05:52,520 --> 00:05:58,430 So this line is called by chemists the equilibrium. 90 00:05:58,430 --> 00:06:03,232 A meteorologist or somebody who just reads a weather report, calls this 100% Relative Humidity. 91 00:06:03,232 --> 00:06:08,446 If you have a temperature and 92 00:06:08,446 --> 00:06:13,804 amount of water vapor that's 50% of this, halfway between zero 93 00:06:13,804 --> 00:06:18,890 and that line, you would call that 50% relative humidity. 94 00:06:18,890 --> 00:06:20,880 Or, if you're higher than that it could 95 00:06:20,880 --> 00:06:25,180 be, say right here might be 200% relative humidity. 96 00:06:25,180 --> 00:06:29,130 It doesn't stay 200% relative humidity for long, it condenses out 97 00:06:29,130 --> 00:06:33,850 very quickly, because this line is where the system wants to go. 98 00:06:33,850 --> 00:06:41,670 Let's imagine we start at the ground and we're going to raise this air up, 99 00:06:41,670 --> 00:06:48,530 and it's going to expand and it's going to cool, we learned that in the last lesson. 100 00:06:48,530 --> 00:06:51,980 So that's this first part of the trajectory. 101 00:06:51,980 --> 00:06:55,680 Let's say that that air started out at 50% relative humidity, 102 00:06:55,680 --> 00:06:59,245 meaning that it's halfway between zero and 100% relative humidity here. 103 00:06:59,245 --> 00:07:05,980 Now the air rising, it's going to cool, 104 00:07:05,980 --> 00:07:10,320 but initially it's not going to change its amount of water vapor. 105 00:07:10,320 --> 00:07:14,180 It's going to move along in a horizontal line 106 00:07:14,180 --> 00:07:19,530 like this, we're changing the temperature, but holding the water vapor constant. 107 00:07:19,530 --> 00:07:24,960 And so what happens is, at some altitude, you reach what's called the dew line, 108 00:07:24,960 --> 00:07:27,380 which is where water starts to condense. 109 00:07:28,700 --> 00:07:31,550 When you start to cross this 100% relative humidity 110 00:07:31,550 --> 00:07:34,520 line, the water starts to want to condense out. 111 00:07:34,520 --> 00:07:40,000 So let's say we just keep on doing that for a while, we rise up and keep going and 112 00:07:40,000 --> 00:07:42,580 we keep the water vapor the same, 113 00:07:42,580 --> 00:07:49,380 we're venturing now into more than 100% relative humidity territory here. 114 00:07:49,380 --> 00:07:54,910 And then at some point, what happens if you get too far above this line is that 116 00:07:54,910 --> 00:07:59,622 you condense and make rain. So you make rain drops or ice crystals 117 00:07:59,622 --> 00:08:06,255 in clouds, and that would tend to decrease the water vapor pressure. 118 00:08:06,255 --> 00:08:11,771 And I suppose it would actually also tend to increase the temperature. 119 00:08:11,771 --> 00:08:15,267 So this arrow here, should probably be drawn 120 00:08:15,267 --> 00:08:18,855 more like that, because we're trading water 121 00:08:18,855 --> 00:08:21,906 vapor for liquid water plus the heat.